Deep Submergence Rescue Vessel Corrosion Studies
These studies were initiated (1) to determine the behavior of galvanic
couples composed of different alloy fasteners in hull materials, other dissimilar
couples, and welded alloys, and (2) the protective value of galvanic
anodes, paints and sealing compounds in seawater.
One set of specimens was removed after 6 months of exposure at the
surface in the Pacific Ocean and another set was removed after 1 year.
Sacrificial anodes protected aluminum alloys and type 321 stainless
steel from corroding; however, they did not afford complete protection to
the contacting surfaces of a titanium-aluminum galvanic couple. Four of
seven sealing compounds were satisfactory sealants at contacting surfaces.
Paint coatings prevented galvanic corrosion ot an aluminum alloy when in
contact with 6A1-4V titanium alloy and A-286 stainless steel only as long as
the paint coatings remained intact. After 6 months of exposure, there were
paint failures on seven of nine specimens and on 10 of 10 specimens after 1
year of exposure.
Effects of Environment on Coatings
A study was completed on the effects of pressures equivalent to a
depth of 6,000 feet in the ocean on the blistering of paints applied over
steel. It was found that blistering of paint in the deep ocean is similar to that
in the shallow ocean.
Steel specimens were coated with zinc-rich epoxies and a zinc-rich
Saran, with and without topcoats, and exposed in the deep ocean on STU 1-5.
After 6 months of exposure, the non topcoated zinc-rich organic coatings
were giving excellent protection to the steel panels, even along a scribed cut
made in the paints prior to exposure. Of the test specimens below, the lowerleft
panel was not topcoated and shows bright steel at the scribe maik. However,
when the panels were topcoated with a catalyzed epoxy (lower right),
a Navy alkyd (uipper left), and a silicone alkyd over the Navy alkyd (upper
right), varying degrees of corrosion occurred.
OCEAN ENGINEERING PROGRAM, MARCH 1968-MARCH 1969.