IIRC, a lot of 'alternate' film capsule plans were abandoned after satellites became able to process and scan on-orbit...
No, It was the other way around. Only 3 process and scan on-orbit reconn sats flew in total (excluding Lunar Oribter). The process and scan on-orbit concept was quickly abandoned and more 'alternate' film capsule plans were used (SAMOS E5& E6) or investigated (PRIME)
The more accurate term is film-readout. They took a picture with film, developed the film, then ran the film through a light scanner that converted the image to a radio transmission that was sent to the ground. You're right that it was quickly abandoned. Here is a quick list of US reconnaissance systems:
Samos E-1: film-readout
Samos E-2: film-readout
Samos E-3: a kind of film-readout, but canceled at the study stage
Samos E-4: film-return (mapping system, never flew)
Samos E-5: film-return
Samos E-6: film-return
KH-1 to KH-4B CORONA (all versions): film-return
KH-5 ARGON: film-return
KH-6 LANYARD: film-return
KH-7 and KH-8 GAMBIT: film-return
FROG: Film Read Out Gambit (never flew)
KH-9 HEXAGON: film-return
KH-10 MOL/DORIAN: film-return
KH-11 KENNEN: electro-optical (beamed its images to the ground)
Film is a very high-density storage medium. It can hold a lot of data. It vastly outperformed all other technologies for a long time. Although the details are classified, there is reason to believe that even into the 1990s the digital systems could not provide as much imagery as some of the film systems for a given period of time.